Hi all, i need yours advice for NAT.

Well, ISP 1 has given the network 165.34.72.0/24 to a private company with PC1 (at the left of the image). In this condition, I don't succeed to understand if with NAT I can to map the IP address of PC1 to the IP address of the s0/0 of router1 (that is 165.34.32.1) or this address is not possible to be used for natting or it's the only IP address I can use. The doubt comes from the fact that others IP addresses do not exist in the network 165.34.72.0 other than 1 and 2, therefore I'm not sure if router1 of the company process the packet with Dest. Addr. different from the IP address of his interface s0/0 and then forward the packet into network 192.168.1.0; normally it will discard.
However I have some difficulty to recognize the
Outside Global address,
inside local is 192.168.1.1,
inside global is 165.34.72.x(?)
outside local is 148.24.50.16,
but i really don't match the outside global. Please if You have a comprehensible explanation give it to me.
Thanks in advance.