The first Microsoft exam you take and pass gets you the MCP Cert...I personally started with 70-270 (Administering Windows XP), which is a good place to start since it gets on you track for MCSA/MCSE. However the choice is really up to you. Like jescab said, just look at their site and see what you want to do.
Good Luck!
Tech Support: "Ok, so your monitor is not working, the screen is blank, and no matter what you do it stays blank? Do you see that button on the bottom right hand side just below the screen? Press it. . . . Great, talk to you next time!"
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Good Luck!