I've seen several people ask for the best way to learn PowerShell. As a person with no previous scripting knowledge, I have been learning PowerShell and have already created several pretty lengthy scripts. So are you interested in learning? If so, here's what I did and it may help you out in the future.
Go through this guy's tutorials before anything else:
http://www.powershellpro.com/
Then go through this book:
http://www.amazon.com/Microsoft-PowerShell-Programming-Absolute-Beginner/dp/1598633546/ref=sr_1_1?ie=UTF8&s=books&qid=1227659316&sr=8-1
Then go through about 50-60% of this book (the rest is too much for an admin and more for devs):
http://www.amazon.com/Windows-PowerShell-Action-Bruce-Payette/dp/1932394907/ref=pd_bbs_sr_1?ie=UTF8&s=books&qid=1227659351&sr=8-1
At the time of this posting, I am going through the PowerShell Cookbook Some of the stuff is over my head but it has excellent snippets that you can use as well as excellent Appendixes which list out common COM Objects you would use as an Administrator, common type classes, etc...
http://www.amazon.com/Windows-PowerShell-Cookbook-Exchange-2007/dp/0596528493/ref=pd_bbs_sr_1?ie=UTF8&s=books&qid=1227659542&sr=8-1
After I'm finished with the Cookbook I will be going through this AD PowerShell book:
http://www.sapienpress.com/ad.asp
PowerShell Technology Center which includes a link to the Scripting Repository Center. Ed Wilson just became the new Scripting Guy and will be focusing on adding lots of PowerShell content to the site.
http://www.microsoft.com/technet/scriptcenter/hubs/msh.mspx
Don't forget to read these PowerShell tips:
http://www.microsoft.com/technet/scriptcenter/resources/pstips/archive.mspx
PowerGUI (Free Script Editor):
http://powergui.org/index.jspa
Primalscript (Not-Free Script Editor)... One thing to note about Primalscript is that 2009 is coming out in early 2009 and will have lots of PowerShell stuff integrated. I'll be purchasing this when it's released.
http://www.primalscript.com/
There's quite a bit of other stuff out there but you'll learn the good community sites as you learn PowerShell and need to look stuff up. Hope this helps!